Fig. 3-5: Density and specific gravity of some common substances. The specific gravity of any substance is the ratio of weight of a given volume of the substance to the weight of the same volume of a given substance. (Where solids or liquids are concerned water is used as a basis for specific gravity calculations, and air or hydrogen is used as a standard for gases). Density (solid or liquid) = specific gravity x density of water (in lb/cubic foot). Pressure within a fluid is directly proportional to the density of the fluid. This relationship can be expressed as: p = h x D Where: p = pressure in lb per square foot; h = head or depth below the surface in feet; D = density in pounds per cubic foot. SPECIFIC VOLUME The specific volume of a substance is usually expressed as the number of cubic feet occupied by 1 lb of the substance. In case of liquids, it will vary with temperature and pressure. The volume of a liquid will be affected by a change in its temperature; but, since it is practically impossible to compress liquids, the volume is not affected by change in pressure. The volume of gas or vapor is definitely affected by any change in either its temperature or the pressure to which it is subjected. In refrigeration, the volume of vapor under the varying conditions involved is most important in selection of the proper refrigerant lines and refrigerant holding vessels. ATMOSPHERIC PRESSURE The earth is surrounded by a blanket of air called the atmosphere, which extends 80 or more kilometers from the surface of the earth. Air has weight and also exerts pressure known as atmospheric pressure. It has been computed that a column of air, with a cross-sectional area of one square inch and extending from the earth's surface at sea level to the limits of the atmosphere, would weigh approximately 14.7 lb. force means also the weight of a substance, and pressure means unit force per square inch; therefore standard atmospheric pressure is considered to be 14.7 psi. at sea level. This pressure is not constant; it will vary with altitude or elevation above sea level, and there will be variations due to changes in temperature as well as water vapor content of the air. PRESSURE OF GAS The volume of gas is affected by a change in either the pressure or temperature, or both. There are laws that govern the mathematical calculation in computing these variables. Boyle's Law states that volume of a gas varies inversely to its pressure if the temperature of the gas remains constant. This means that the product of the pressure times the volume remains constant, or that if the pressure of the gas doubles the new volume will be one-half of the original volume. Or it may be considered that, if the volume is doubled, the absolute pressure will be reduced by one-half. This concept may be expressed as: p1V1 = p2V2 Where: p1 = original pressure; V1 = original volume; p2 = new pressure; V2 = new volume. It must be remembered that p1 and p2 have to be expressed in the absolute pressure terms for the above equation to be used correctly. EXPANSION OF GAS Most gases will expand in volume at practically the same rate with an increase in temperature, providing that the pressure does not change. And, if the gas is confined so that its volume will remain the same, the pressure in the container will increase at about the same rate as an increase in temperature. Theoretically, if the pressure remains constant, a gas vapor will expand or contract at the rate of 1/492 for each degree of temperature change. The result of this theory would be a zero volume at a temperature of -460 deg. F, or at 0 deg. Absolute. Charles' Law states that the volume of gas is in direct proportion to its absolute temperature, providing that the pressure is kept constant; and the absolute pressure of gas is in direct proportion to its absolute temperature, providing the volume is kept constant. That is: (3-6) V1/V2 = T1/T2 And (3-7) P1/P2 = T1/T2 Where: T = absolute temperature; P = absolute pressure Or these may be expressed also as: V1T2 = V2T1 and P1T2 = P2T1 |